Hierarchically Porous Polymer Monoliths by Combining Controlled Macro- and Microphase Separation

نویسندگان
چکیده

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Synthesis of hierarchically porous polymethylsilsesquioxane monoliths with controlled mesopores for HPLC separation

Sol­gel synthesis of macroporous polymethylsilsesquioxane (PMSQ) monoliths has been successful over the past decade, and applications to separation media have been investigated. However, the control of mesopores to tailor hierarchical porosity, which is promising for improvement of the separation efficiency, remains challenging. In particular, an independent control of mesoand macropores has no...

متن کامل

Phase and microphase separation in polymer blends

When two different polymers are mixed, they usually demix because of the slight repulsive interaction that exists between their monomers. This is general and may be related to phase separation in two component mixtures. When the same polymer blend is cross-linked in the one phase region, elastic forces develop and do not let this to occur. There results a microphase separation, with coexistence...

متن کامل

Methacrylate Polymer Monoliths for Separation Applications

This review summarizes the development of methacrylate-based polymer monoliths for separation science applications. An introduction to monoliths is presented, followed by the preparation methods and characteristics specific to methacrylate monoliths. Both traditional chemical based syntheses and emerging additive manufacturing methods are presented along with an analysis of the different types ...

متن کامل

High-pressure electroosmotic pumps based on porous polymer monoliths

Electroosmotic pumps have been prepared using macroporous polymer monoliths with their pore surface grafted with the ionizable monomers 2-acrylamido-2-methyl-1-propanesulfonic acid and [2-(methacryloyloxy)ethyl]trimethyl ammonium chloride, respectively. The effects of critical parameters such as pore size of the monolith, percentage of ionizable moieties in the grafted layer, crosslinking densi...

متن کامل

Mechanically stable, hierarchically porous Cu3(btc)2 (HKUST-1) monoliths via direct conversion of copper(II) hydroxide-based monoliths.

The synthesis of highly crystalline macro-meso-microporous monolithic Cu3(btc)2 (HKUST-1; btc(3-) = benzene-1,3,5-tricarboxylate) is demonstrated by direct conversion of Cu(OH)2-based monoliths while preserving the characteristic macroporous structure. The high mechanical strength of the monoliths is promising for possible applications to continuous flow reactors.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Journal of the American Chemical Society

سال: 2015

ISSN: 0002-7863,1520-5126

DOI: 10.1021/jacs.5b04992